Induced mirror symmetry breaking via template-controlled copolymerization: theoretical insights.
نویسندگان
چکیده
A chemical equilibrium model of template-controlled copolymerization is presented for describing the outcome of the experimental induced desymmetrization scenarios recently proposed by Lahav and co-workers.
منابع مشابه
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Experimental mechanisms that yield the growth of homochiral copolymers over their heterochiral counterparts have been advocated by Lahav and co-workers. These chiral amplification mechanisms proceed through racemic β-sheet-controlled polymerization operative in both surface crystallites as well as in solution. We develop two complementary theoretical models for these template-induced desymmetri...
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 30 شماره
صفحات -
تاریخ انتشار 2012